Theory of Unimolecular Reactions (Slater, Noel B.)
نویسندگان
چکیده
منابع مشابه
Revisiting falloff curves of thermal unimolecular reactions.
Master equations for thermal unimolecular reactions and the reverse thermal recombination reactions are solved for a series of model reaction systems and evaluated with respect to broadening factors. It is shown that weak collision center broadening factors F(cent) (wc) can approximately be related to the collision efficiencies β(c) through a relation F(cent) (wc) ≈ max {β(c) (0.14), 0.64(±0.03...
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The results of two time-resolved experiments using femtosecond laser pulses are presented. In the first, molecular photoinduced detachment of I2 from methylene iodide is studied. The progress of the reaction is monitored by selective detection of fluorescence from the iodine product; molecular dynamics are probed by depletion of the fluorescent state. Pump-probe spectroscopy of the halogen moie...
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The blackbody infrared radiation induced dissociation of methyl benzoate (C8H8O2(+*)) radical cation was investigated by using a Fourier transfer ion cyclotron resonance mass spectrometer equipped with a resistively heated (wire temperatures of 400-1070 K) wire ion guide. We observed product ion branching ratios that are strongly dependent upon wire temperature. At low temperatures (670-890 K) ...
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ژورنال
عنوان ژورنال: Journal of Chemical Education
سال: 1960
ISSN: 0021-9584,1938-1328
DOI: 10.1021/ed037p552.2